By Nabarro F.R.N.
ISBN-10: 0198512449
ISBN-13: 9780198512448
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Example text
MILLER ET AL. Soluble Polysilane Derivatives 45 Table I. 3 Table II. ; ACS Symposium Series; American Chemical Society: Washington, DC, 1988. 46 INORGANIC AND ORGANOMETALLIC POLYMERS Spectral Properties and Polymer Morphology One of the most intriguing properties of catenated silane derivatives is their unusual electronic spectra (25). The observation that low molecular weight silicon catenates absorb strongly in the U V was first reported by Gilman (26,27) and has been extensively studied (25).
A) W. I. Patnode and R. W. S. 2,381,000 and 2,381,002 (1945); Chem. , (1945) 4888. (b) See also: Α. V. ; ACS Symposium Series; American Chemical Society: Washington, DC, 1988. 42 35. 36. 37. 38. 39. 40. 41. 42. 43. 44. 45. 46. 47. 48. 49. 50. 51. 52. 53. 54. 55. 56. 57. 58. INORGANIC AND ORGANOMETALLIC POLYMERS Topchiev, N. S. Nametkin and V. I. Setkin, Chem. , 4 (1952) 508; Dokl. Akad. Nauk SSSR, 82 (1952) 927. G. Fritz and A. Worsching, Z. anorg. allg. , 512 (1984) 103. S. Yajima, Am. Ceram.
Crosslinked network-type polymers are needed. Such structures can be generated in more than one way, but in the case of the polycarbosilanes they have, to date, been obtained mainly by thermolytic routes: thermal treatment (with or without other chemical additives) in the case of the Yajima polycarbosilanes and the thermolysis of t e t r a methylsilane in the case of the Bayer process-derived polycarbosilane. Although we have not discussed other types of polycarbosilanes, some may be mentioned to show what is available in terms of other specific examples of general formula 1.
Theory of Crystal Dislocations by Nabarro F.R.N.
by Anthony
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