Download e-book for kindle: The Development of Quantum Mechanics by Harrison D.M.

By Harrison D.M.

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2) Thus if you have not yet studied differential equations then simply use Theorems 1 and 2 as a recipe for getting the answer. Then check your answer always to satisfy yourself that it is correct. We have now finished our discussion of ordinary differential equations. We are not going to consider equations with non-constant coefficients. If you are interested in higher order equations with constant coefficients then these are easy to solve once you know how to solve second order equations. See Purcell and Varberg [Purcell 1987].

Let’s call the constant E and make both sides equal to it. 11) f dt i¯h ¯h and these are just two ordinary differential equations, which we know how to solve! 10) is only a function of x and is called the timeindependent Schro¨ odinger equation (for 1 particle in 1 dimension). We shall spend a whole chapter on solving it for different potential energy functions U (x). That is we will get different solutions ψ(x) depending on what function U (x) we put in. 11) can be solved right away because it doesn’t have any unknown functions in it.

18) a 0 which gives Footnote:The integral is easily evaluated using cos 2θ = 1−2 sin2 θ where θ ≡ nπx a . D2 a2 = 1 giving D = 2 a. 3. Recall that the value of n characterizes the energy level En . Thus for every En there is a separate ψn . 4. 58 CHAPTER 3. 1 Check that ψ2 (x) = Solution We need to check that a 0 ψ2∗ (x)ψ2 (x)dx = = sin 2π a x is normalized. 2 Check that ψ2 (x) and ψ1 (x) are mutually orthogonal. Solution We need to check that Define I ≡ a a 0 a ∗ 0 ψ2 (x)ψ1 dx ψ2∗ (x)ψ1 (x)dx = 2 a a sin 0 =0 2π π x sin x dx a a π π x cos x dx using sin 2θ = 2 sin θ cos θ a a 0 π π π Let u = sin x ⇒ du = cos x dx.

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The Development of Quantum Mechanics by Harrison D.M.


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